USPTO Patents Application 09993647

PATENT ABSTRACTS OF JAPAN

(1 1 publication number : 02-035450
(43)Date of publication of application : 06.02.1990

(51)lnt.CL

G03C 7/34
G03C 7/26
G03C 7/305

(21) Appiication number : 63-187778 <71)Applicant : KONICA CORP

(22) Date of filing : 26.07.1988 (72)lnventor : KIMURA TOSHIHIKO

SHI NBA SATORU
KIDA SHUJI

and the graininess of the photosensitive materia! by
incorporating a specified cyan coupler and a DSR
compd. in the photosensitive material. ...
CONSTITUTION: The phenol type cyan coupler (A) " w ' <■ " s

which has a group shown by formula I at 2-position of f ,

a phenol nucleus and a group shown by formula II or
III, etc., at 5-position of the nucleus, and the compd. ^
(the DSR compd.) capable of being released a

oxidant obtd. by being allowed the compd. to react 1 r y-

with the oxidant of a developing main agent, are
incorporated in the photosensitive material. In the
formula, R1 and R2 are each (cycio)alkyl group, etc.,

R3 is alkyi or aryl group, etc., K is 0 or 1 , R21 is hydrogen atom or alkyl group, X4 is
>NR22 group, etc., R22 is (cycio)alkyl group, etc., X5 is an atomic group necessary for
forming a ring together with a group X4, X6 is a substituting group, (ml) is 0-10. The
component (A) is composed of a compd. shown by formula IV wherein R1 is C2H5 group,
R2 and Z1 are each hydrogen atom, R3 is C16H33 group, etc. The component (B) is
composed of a compd. shown by formula V,

(54) SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL

(57)Abstract:

PURPOSE: To improve the red color reproducibility

compd. (its precursor) which can scavenge an

http://wwwl9.ipdLinpjt.go.jp/PAl/result/detaU/main/wAAA9CaqTtDA402035450Pl.hto 4/9/2010

©&lf 4f fF&# (a) ^2-35450

BBSB^ JtWSS## ¥^2^(1990) 2 ^6 8

7915-2H
Z 69G6-2H
7915-2H

H 187778
@tB R Hg63(1988)7 H26B

@£ @g A 2 ^ £ £ tk S^«Ff?&ESSfWlTi26#2^-

©IntXL*

G 03 C 7/34
7/26
7/305

# m m

i . & # <o s fts

o y v ft a* a ? - ^ $ # tt *4
2- *f ^ Iff # <0 *£ BB

$ ft $ ji ^ ft < £ *> IT SB & ft ft AS , « 3K ft &

« ^ v ^' l » * ^ ft *» ^ ^ a , * <r> m # £ &

7 * / - ;U ^ 7 > ^ ^ - :

tt T & £

-477

Xtt -WHCO— t' Of* SHt5 ? * y

•> 7 V 7' 7 - a

C Ji JSE <0 3£ 4* . R,ZSLC/R,lir^*A'S> ^
a 7 Ji> * ^ 2£ r^t/^A^JlJ-^SXliT^a
* - ;U g £ , R j li 7 ^ ^ ^ 1 ^ '> * n

7 >u *- S , ry-^^xii^T^iitv k it

0 x (il t ^ L , s , ^ ^ 1 ^ 7 /u ^ ^ 1 o i: ^

r , *± & < £&2{&^&&®^t$rt6&'C£>

R , 2 li 7 * ^ S £ , LlilK^mT-Xfi^lt^^
7 > * a- 2£ * r u - s * •> V D T ;u * /u H , ^

raE&is, — C0C0)aiHi3. -~CONR 13 El4, -or,
-SRjtv— OSOjR,,* — S0jC0)fi)Ri.v — MR i tSO , R i i
- SO j R * t R . * X (± ~ HR j , COR i fl Sr * R m l± 7 A- A-
K X II 7 D - ^ S t v R . * *± * & JBC x 7 A- * ^
IXU 7 y - H- g * fl , 2fc ft i tt 0 X ti t £ ^ U

C , - 0 <0 £ & R , t ii r y - a* 7 + a* as x t* fl- tfc

7 ^ t A' s t o t ^ v Riti±'Mte<tb2m

U - A* * ;u * v r 5 KSXIt - ^^^7 t «

* ^ i!S , X , i* ft & & * > fl 3 li G ~ 3 £ $ L ,

R , , li tK $ ST =f X li T ju * ju & «r , X * (i
— N—Ri j X 11 -C-R*, fc, K 4a li r A- * *

■y ? a 7 a- * /w S > T V - A* S > ^ f- o Ht X *i

- X T - R , * £ , R ls tt/^y '/ff^, r ^ * ^ at ,

^ o 7 ^ + ^ a > r y - s » ^ r p I i X i±
-Xt-Hh^ R ti ?k * ^ * /* u Y >- Iff * ,
7 ^ * ;H , ■> ? u 7 ^ ^ ^ S h 7 'i - /l' fi ,

> M 7 A' * A' it » 7M-~vU^Xli^^ CT &&£.
X r l* - CO CO) as - .-S0»CNR,*)" f - * f* ™ CONR S(

- , 0 Xfi 1 ^ R z.H**!^ v 7 '/t- *
A* £ v '/M7ju^^S» T y - ^ £ X li ^ r o

mm * * x * & x i t & & m * & ft + & * z & * 1* ft

»15B¥ 2-35450 (2)

& JS* JKS ~P # £ . X E ti S & & £ > B,liG~10£fl

X . *> ^ ft *= * *? 2aft&-k<7>#fttt$r^$

i- £ ff) £ & O • )

3 . & 93 <0 ^ 19 & R J

C A US ± <r> f "J ffl t> if )

# jfe W I* ° V v ffc » * ? KM

t 6 *> <?> -c ft . #£fesa&fctf®#&K«ft

0 & W <?> W * J

t* £ i, < * &@3a<t£ft

t» , & s Jgi £ a Iff # ^ ^ * 5 ft ^ ft * J= ? * ° x

$ tz ^ , -e n *> # # - & <?> * - *f ™ ^ -t- # ^

j^co^< k ^ >n; (i l u t ^ f ^ a ? - i£ & $5

£ W <?> H £ & ii 3£ , *3M~&?f&&<7>#tJb£

#^-*tf$ft#nKffl^^ft£*>^ v *7'^ t
-^*'/7v*/7-"*«l!6*>n6«i:i&fTti/;

«fcfett<tt&Jt!llfc#»Ufc*^4^&7x/-~A> *

1363-161450^, !B|63-16U51^#K * 7* 7

^!3l(/^^»HtOI^ 9 ~ J8S # # K

ffl ^ fc « , ®fe|fc(7)&#rt;£<^ + #-^fc&-

t -C ^ & ^ C £ ^ ^ ^ ^ ^ t£ -o fz. &

C 2£ ^ « B ^ 3

# a # *> @ an* , ^aowms*s*»^n, u

-478™

^ C t K ft & o

^ tf> « fia: j

* JS K tf> I W . 4* * ^ ^ * < t t
aYx<fc»j«f7«^»!8S3fetsr**Kt?^-C

rlfi»ft»«r^*^^^L^*<t^*ft

7x./-^^->'7> r ^/^™" :

li >

Y

2 ffi K

- NHCONH-

N

«: m U , 5 & &

f

-NHC0C-S0:—R t li,
CR*)k

Xt± — KHCO— C ^

Ru <5^ e *
-KHCOC — L-

ft. i CiOfl,

■> T V ft ■/ J — o

km^m*?, vl s &xf r t & r & * a, m > ^ a

7 }V 3r A> 2c v rJl'^l'AA'^-^lXliTA'^*

/U *tf .r. & fc * R iliT^t/l'S, V ^ w 7
^ * ju £ > rU-A'SfXti^f-ogRS*^ k a D

R , , li 7 ^ + ^ S X i± V M r ^ * Ji- 1 4 , R i !

x 1 1* ^ o y y ^ , c r / s , r a,

4r M , r y - )V & > ■> i? o r ^ * ^ 1 , ^ f- o
83 3£ , — CO(0)e 1 R I1 ,'"CONR,iRi t , — OR , s , — SR , , ,
-0S0jR t js —SOjCOiflsRii, ~~ NR , ,S0 * R i s ,
~ SOiR i iR n X i± — MfiiiCORii^ * R t » (i r * A-
K X 11 T !) - ^ S * » R . i (* * * J* ^ * 7**4*
as X li 7 'J - ju 3S fe s fl,&(/fliiiOXfilfc3SL*

7 * * ^ 2£ "C £> 9 , O , R i * li ^ V < t h 2 IB
<n&&n***Slr&Tn,*R>m-f!h*>* X 3 U 7
y - ^ x ^ * v 7 5 n X li 7 'J - ^ t *

»BB¥2-35450 (3)

4 ju & £ , X » a R tt S * , $ ? !i 0 ~ 3 £ & U ,
e ^ 2 — 3 ^ S#Xil*PI — -cfcftfc^TfcJ: < ^

-A— R», X t± — C— R,» £> Kti ii 7 * 2£*

Horj^^i, r 'j - m , ^ "r * m & x i±

- Jf , - R a 6 * > Rnli ^° Vvg^, 7 ;u * A- & .

v- ? o r * >v m v 7 u - m , ^ T ° & $ X II

- X i - R * i * ^ R 2 . fi & & & * ^ d y ^ Rt ,
7 ^ * ^ % , ^ £ o 7 A> * ;U £ , 7 l > - A- & , ^
f aS!lX[i-)t,-R tf K R : s fi 7 ^ * ^ ^ >

* o 7 * * ;u a , ry-zuxn^f^isi^

X , ii - CO(0)n* «- ( -SO:(NHM)«H-Xli - CONRt *

- £ , 0 Xi± I ^ R ,,lt ^ » 7 t
/u 3E * M 7 ^ ^ a- S * 7 U - ;u at X l± ^ ^ «

& #l $ # £ , X , (i K & & £ * « t fi 0 ~ I G & i£
U , nitZUJiOi I & X.(i|Si--P^<E-5 < C
<fc t s * X * Ri-~Ri.Rii,Rn.ft2t,Xi~Xi

$ & i ~ 20O t> *> * t <> ft K 2 - Ho M
R , t l ^ a S 7 ^ * ^ I i t f ii . $ & & t

- H ti O iS« Iff H ^ o

R i.R*tR ? *C ^ £ ft £> *>^u7/W*^3£t U

R , 3St R % "C 3R £ ft £ r^^A-A/nS-^S*
7 ,u ^ * > * A ~ A & £ L T ti . J*t ft ft 1 ^ 20
W7^*>H«»t*t* t> *> ^ UP * U ^ -

R , t ^ ^ 5 7 ^ I H T l± > ^^Stl

~ 2A<n * (T> & ft ± \* < <> 7 U - ^ ffi t L T (i , J*t

li , ^^ofiC^^gllK, fift sfS , ?K ft a ff ft &

-479

0

4

0

R ,E

s

ft -6 ^ & it

(i

m

if

t

K ^

&

o

>

I

8

7

% >

# if

ft h

i £ ft ^ ^

r 1

£ ft K «

H

r

i± ,

*.

if

✓■^

u

y

v 0K ^ ^

If iZ T

7

y

7

n

, 7

7

f-

7

y

A*

> t

K o

A' *

7

+ >

fj

A- *

7

y

* >

ft*

w 7

•>

ft >v

;u

7

•V A-

* *

->

7

• K

4

7

K ,

T ju

7-

7

U

;u %

« #•

s6« ^ if

ft

ft

h

i±

IE

it ft £

^ (0

& V

R . i

m *

ft

7

m

t

U

"C

li

, JK

ft 3R

i

24<T)

cr 7

;u

ft.

m

3 -

s

A

<7>

£

U

<

, R

1 1

7

7

2£ t? * 6 .

c ft

6

7 A- *

a- Hi

t I t li , iK^Kl

1 ~

10) <T) b

tf> ff 4 t < , X t T^

i m A

r

& A*

&

t L, T

a ft

m & I ~ 2K<n t (0 ,

7 y ~-

t u

r

(± s Jft * &

6 - 24^ t (?) h > ^

O ~f /U-

;U

£ *

L,

T li 3

- 8

as c

r

t*

IE SK

,

$ O 4

7

£ CO

b

tfT> ai< »

t L

< , R t , F R i i X X

$ n 4

7

* A-

&

& L T

f± ^

r y -

r

(i K ^

fit 6

~ 24<n b v> & , h t

L t li

m t- ^

^ fl

R . *

-c

S S ft

6 #

H

(a

% IS £

U X

it , m i ti ^ ^ y y

& m »

> 7

j m , ^ > o * , ^

y 7

^ /

£ C tt & r 5 ^ n ,

& tfc r

J

m £

^ tf

£ ft 3

L, X tf S£ 38

, fSi It

CO

b <r> ri< G? * t

x s tz X *) J& n

mm***

r o

t <

t J: ^

t

K D

H 7

s / a c £ « r s ^

g > &

r

* £ O

) V

T / m > ~ V n S ,

ft

■>

?t ;u * 36 ,

7 4r ^ & , 7 *J »

->*

?

p 7

* ^ 2£

> ^

(X (S

R

* » tt

Stf iffi <o b

r m ) a* # <f h n * ,

R is

R

^ n £

O £ &

£ i U

, W jL If W J£ ^ R 3

r s£ *

n

m &

t

t L t i ?Ta f; ^

J!>< ^ if

& Jb m

7>^r^-o4 }j c

u

fi T IS *s <o ^

<0 T? A ^ o

Wfflf 2-35450 (4)

* , I^E^^^LTiis « i. If ^ t» y v Iff f . -
y Is r i /1CII7 ; at ** 7 1 ✓ & fr

g o ) *i ¥ if i? n 4 , x t £ t r w i;: jf * u ^ co
its r / a , K*»i-4<or^*

^ 7 i f & fo & .

X ,t t T li 7 'J - ^ ^ ^ * > 7 a F I i4 ! tF t

l < , aft r y - ^ *s t± at si ai c a t k ° * ^>
, » /u iff * i > ^ m ) t|t^^5:tt l o

/C b <T) ^ ^ tf <b ft * „

hir^*^2Siit(j:Ki(ES:l~2^^, ■>

^ o 7 ^ I H t in - 8 1^ H . 7 *J -

ft •> 7" y y m u j£ ^ u t *± H ^ ^ ^ o y y

tit * a. & ft m s %tm, it us m t # ) , r 4 /

S < ffl ^ If 7 * / s 7 v 7 * / , & T ^> A- 7 5

7 ^ t 7 J / , 7 U - ^ 7 W I ^ } , 7

/ J£ , 7 U »- /u ^ * ■> 3£ C ffi Jt ff p - > h * *s v x

-480

/*'> s p- -? 9 V ?, * y 7 i K 7 * ✓ * ■> „ P -

# ,u * * > 7 x / * i£ 3£ ), r >u a + 3B ( 05

y h * > , 2- > H * > * b * > 3£ # > * ^ y

- ;u f- * m Cfllx-ftf^xnA.**,. 13 " * JV * * ^
7 *~fl- *

f-^^jt". 2 - fc |?d t ->if tlf ) , & &

31 * * £ (fll *- I* I - * * ^ ^ I* ? / - ^ ~S- f- * 4
;u , 2 - tf u ^ * * K 9 ) , ft 5R » C « ^ i* 1 -

t* 7 / y ^ , l - < i ? "/ % > ^ * 2 , 5 - tr 7 y 'J v

^- y - 1 - A Ws ^ ) ^ * ^ # * ^ ^ ^ ^ X ^ * & s

7 y - * * * n ^ *

=. A, m . 7 ? * * * * * ^ ^ - A- & #

^ n ^ o

^ c tills ^) v 7 y / 7 - iO^^^^klTt:^
■* . * & 93 li - ft ^ ^ K 56 <* n 6 ' i «o t? li ^ „

OH

R*— SO,— |— OOMH;

(5)

-fVc

8 -C*H*

9 -CnHj

10 -C,,H*j H

Ho,

R j

z ,

1

N

Z JL

2

•C*HiCO

H

"li! til J J

Z A

3

H

-CHs

Za

-C t H»

If

Z A.

5

H

'Ct flHa a

H

6

-CHi

H

-CHCi oHt s
CGQCHj

Za

7

-CHj

-CH 5

Za

>NHS0 8 Ct*Hi j

0OH

OH

No. R

OK

12 *C*1{ 5
15

17 -COidH;

H

i& -COC,H, s H
19 ^) "

20 -CH,

— 0

It

ICHj

OCH s

OSOaC, 6 Hu

16 -Ci*H?i » ~\ /

-r<"

X5

-CHC lt Hsi

i

CH,

No.

CM

R j i ft i

26 -Ciolhi H "Cfl

21 -C 1C K,, H -CN Z A

22 -C, 0 H,i H -COOCH, 5-NHSOr^^^~OH Z A

23 -C lB H,, H -NHSOiCUj 5-NtfS0 8 -^\-OH Z A

.COOli

25 "C Ifl H,i H "Cft 5'NHS0 2 -^^ Z A

/OH

Z A

-481-

^¥2-35450 (6)

W ± J(G ^ 7 * / - ^ 7 v ^ / ^ - it , $1

£ tf t K o * '/ ^ iS t * S t ft: 7 5 y ^ h o 7 i
z - ft i: p - > r y 7 x zl ?\* < v *>■ 7 t- ~

* ^ i tf) ■> 7 ■/ ^; / 7 - (d , f&##*44*?>$;#
14 /mj y « ?L)« 1 4 1/ < W v * O B$ W » t? 1ft
js?*tt&c£#flT*b<* it ^ i it ^ o ^ ^ ft
ffifLjsq)9'cff*L<tfrffl^n*» sfe j« *
<b « ?L 3W ffl »i » &ffi&£ffifiKge*0 2IBfta^lii!5

, fS ^ ^ ^ 3 l» *^ )5K ^ t ^ 5 ^ i f L <

i» f n tf) i c ut i i < m #? n 6 •

3UD m t» t < li l» % W # £ t & » y v ft ffi I
*;uil9 I x !0 _1 ~ 1 ^ , I Kf n < II M
1 0 - 1 ~ 5 x 10".' * ^ tf> S ft $ *

* Sfi W <?) > 7 v^7'7»f±^^t t ^^UT:t3 2
«WitflffflLt^Jti«i'% JG K # 55 18 «

-482--

& i t> # ^ *

# & 91 K *S l> v "C 1HF SB #
U ft

# & , ^ x. it £ » <0 ^ 7*

U ;U st; 7. 7 x — h , #

7*7-t*n^n*aT?

U ft fc S , # ® & #J £

-£L, #;^

IL ffj *P K It 4H «s #D ■* £ ^

t 7 b U Ift * JBB Wr L ,

i: iSs Sn L t ^

8£$3<7)->7va7*7-fr

6 It ft i: li , $ 3fc ft & <r>

+ & 7 ? u- - h , h V ^

y ^ ^ 7 x y - /u <7) c

^ h 7*ttfcT:*vgi&$£<7D

^ R i: * IS 5i ^ '> 7 y A

&tr-tf7^>'zltg?sE£a£

* x i± =» » -f n ^ 6

, X Jb & ft ft # & & £

* S£ U f£ , i tx Sr ft 5R

ft & i# ft £ *> I* £ *= * 0 * 3Lfft£3£<oJS*t*fc&ft
i r A y ^ v t ffl S ft ^ ft ^ ^ 11 * * air w

ft £ ft ft U f# -6 & ft C W T rosRft * m J £ ^ t & )

(I o ^ X m m -t 6 * » DSKfb It i L> < i± -

- m * cm

tf^frSLft**?'*--***** T I M E Si * 7
y y x <fc ^ 'C Coup^^PftBtS H tz. i& *

u 1 t » t , s C li a*' 0 li * 7 / 'J >

»^«*oeaffc^^ft**»fl;SJE* * ^ u v ^ #

j£ f i: i D x a * v ^ U f* 5 * * * ^ ^ * - £ fc

If BB ¥2-35450 (7)

I±i«ft*i|!fl«)Kj|lfetf) * 7 3 - & M -C & 9 ,

cm £ ffl 3

R l COCHC0NHR 2 -J

-git^ craj -Jffl* cm

Jh ^5 - & & t II 3 i;t>Mt6R,ti7^^H,

t v - a, m * ry-^rw2s**u, r 3 7

y - IE . 7 ^ ^ jL' ^ t ^ t s

_fc 35 — Aft s*; c m 3 k # ^ r , r a n r ^ * ^ ffi ,
ry-JvffitSEU* R * (4 , T a-S, 7 <y ;u

7 w ru-A-ri^s, 7 y - ^ ? ^ k

JL IS - Jtt & C JV 3 K # ^ T * R * li - a * C Iff 3

^r 4 £^^^&9, r . i± r -y ^ 7 s / a * * ^
* v 7 s k a * r ^ * a- Sfi , 7 ju = * s , ^ °

y v SC ^ t S t .

W I- Jb » — Jitt * C V ) 3t t/ C VI 3 (i 4J tt ^ K ft

3S R T li 7 ^ ^ ^ g , 7 ■> - ^ 2£ * 7 y ;u 7 i /

a v 7 y - ^ 7 i / m •> r a- * * v 1 IS - r y - a-

u 4 K $ , 7 ;u 3r ^ ? U- ^ F S t S t . R * li
7 rt, t ^ I » 7 'J - a, K t S t .

-483

_fc Ifi - Aft 5$ C V3 D Cfeit^ R 5 ti7 ^1^7 ^ ;

R ( li y vg^, 7 a * a- 2£ . 7 a * * -y g „
7 -y >u 7 i / & * * /U- * > 7 5 K & |$£ "if" *

j. gg _ ^ ^ c VI 3 ts ^ x , R 9 t* - ^ 5ft C VI }

(II} Cfc^TR I- dS, 7

> ^ 7 U I , a ^ ? fflE •< 5 K ffi , ?t ^ * V 7 i

FJ, 7 /u- ^ ^ -y s , 7 * ^ 3£ v <^ p ^ y SC ^ „
•y 7 ^ £ t ^ t *

* it , Jb 383 — * C VO 3 *r J: Of C H 3 K ^ It 6

pi±o^^u2«o^ifc*^u, -biE-sa^; cvi3
K & £ q l± 0 ft (' > u l <o si as % ^ t *

3£ v 7 / W v a y 7 5 K 3fi . t K p ^ -y ju-

3£ , ft ^ * * > ^ S£ , 7 ;H s r ;u = + -y S ,
fl^rt?2^t*^Sv t ^y ^ 7 • / is . 7 y - a,

i ^ f£ I (i n 6 t> O T ifc 5 c

?»BB ¥2-35450 (8)

i„n-r^;^itu,^aRn?)iti tir is - tt * CM ir *y ^ r , t i m e -c » * n

&&£H£&$^^rt/7-^^#,S£Ri&^L & 4* , B (i ^ v v a * fc li t ? ^ t' v a t «

& # to ^ m n w *= * a ^ * / ? - ^ & i* i s r , *

^ ™ ift ^ ^ -s-*fct4-N«*r»l-* site — ci^ <r>

l r '> ft < t t — ^ ^ ^ * * s ^ 3£ s r y — ^

R

* s l. * t t - c - s » y c ^ l, * * na * /; t±

J 3

5t * , Y > R * « , Ri>tt&*flff£-Jtt5S; U3

t PI Jtt A 0 > R , Hi * 3PS ^ * 7 ^ * a- £ s T

V ™ ^ 2& s 7 ■> >u H v * /t- * ^ SE * r v #

,u ^ ^ £ v £ /ifd fc£3£^£K2t£S:^ Us R , , li *

6 ^ > r * a- s * r y » ^ as ,

7 A, 3 * jl , Ti/^s » 7 i h' S , X ^ * V
r i !■' ^ v a ?H * ffi * r ^ a * '/ * - ^
g , A ju /< ^ ;u S (i 7 / S t S t ,

s , ifo ss - Jtt a C xi D ras^nfi^^ay/
3i *± , mr as — « » c x 3 t m m it , y^co«p«

® t£ & # l * - c - ^ s c i; IS ^ l t ^4 s

R t j

&cfr*f*?#«£HtlftKf£:K:J:!? 5 c £ & & t &
— « 5*5 C XI )

# ^ . n u i± is ^ o is ia * > «a « * /- i± a

-484

■f

■J

/ & iz

*£ L T J*

0 H

E

1*

f* ^ ft

#

^- >u W

, f 5l- ^

$

S

a f- *

«:

U

h * 18

4:

m u ,

c (?> * n ¥

& B

S

C

AD

ft ^ (t t t> t C oupA» f> N u*« ft W ^ n f: a , 3^

e # as * s r .

Ift 3£ 3R K fb # t ^ * v -f 6 f= f± , E^x^-<.

^ , ^ ^ ^ Angew, Chest, lot. Ed., 1 7 875 -
886 (1973), The Theory of the Photographic??*
ocessffi 4 IE (Mac Nillan 1 977 ) M m , ^113^59-

h £ ^ . A ft W 1= II S fe

R

T ;U * A- > ■> ^ ° 7 ^

^ ;u , r JU y r. , 7 U —
&<£fc2"?W**7'J-

# u < , t t t r y - ^ IE

S 1 (UT H ^. S C <?>
C R ) ^ U ( EE ) t? $ cF
§ #j tc ffi D -c f£ « ** 35 f* n

h ^ 1 1 £ t= a j*j & * *
s c^Waftaafc^aw'* 6 —

% \' &? t t < li ! 5 ~ 4 5 -C ft

ffi $ & » li , S C i7)

i L < ti B -20t ^ 6 ,

n -f y v ^SlEi: J: 9

x * ^ v -T 6 x ft ^ v i>

s c iit««i^ss««i-ii

h •

DSRffc <f> A ft Wto fH

^ t- a & £ # KF

s*« fSF % U < > ? * ~ iU

gt & & s ± ib - ft *
h ^ , * & en <t> ft * *

& 0 3 it 5 it ft (i *
50, (f £ L < tt 10- 45,

3R (ft: O l£ fP 14 6 - 30,

* ™ -c £ £ , 1£

fe ^ # ^ ^ _ ^

WHT2-35450 (9)

Ktt St 1546837 * . W Bfl BH 52-15063 1 ^ , R57-1U
536^, R57-11537^, jS] 57 - 1 38636-^ , M 60-185
950^ . m 60-203943^ , R 60-213944-^ % TO 60-214
358^ , ^ 61-53643^ , R 6 1 - 8 4 64 6 * , 13 6 1 -8675 1
fB| 5 i - S 02546^" , ^61-102647 ^, R 6 1 - i 0724
5^, 13 6 1 - 1 1 3060-** 1^ 6 1 -23 1553 ^, 6 1 -2337
U*, [S] 6 1-236550^ , PO 6 1 - 2 3 8 5 5 1 * , i^61-238
057 ^, |W| 6 1 -240240 ^ , R 6 1 - 2 4 9 0 3 2 * ,
638^, m 62 - 205346# , FS 62 - 287249* « K K lift

& dsr ft £ <» fc W a* 1" * > *«^ ,iTSfl
7f, ft if ft £ K 56 * n t> <?> ft fr ^ •

D S R - t

(CH J ) 3 CC0CHCQNH-< ?

£ L t l±,

* l±' &

NHS0»CH 3

CH, iCt)

M<0

D S R ~ 2

CH:

COCHCONH"

NHSO*NCCHi)t

Ci tH«iOCOCHOCO

!

C6

NHCOCHGONH^ J

0 COOCHCOOCkHjs
OH i

CjHtNHO

Oil

D S H - 3

<CHj)sCOOCitCONH
0

1IO0C

CHs

CsBttCt)

DSR

COCHCON^i

D S R - 7

MHCHj

C00C IZ H J6

0 S R - 4

CCIIOjCCOCHCONI!

-Q

^^^x CONHCHjCH 2 COOH

(CHOsCCOCHCOMH 1

0 x NHCO<CHj>jO-

0(

-CH 4

CH 3

CtHuCt)

C*H,.Cl)

-485-

D S R ~ S

D S R - U

»BBT2"3S450 (10)

Cfi

(CHQ.CCOCMCONH^f^

0 ^^-NHCOCCH,):

*Hi,Ct)

o-O

C s Hi,Ct)

CH,

D 3 R ^ 9

Cfl

CCHOiCCOCHCOMH" ^

tl N ^CHi

D S R ~ 10

HHC0C, 3 K,

so t m~xjy — o-i [p NH(XT^_7

$3 >IH00CH,0-*

sa 2 NH

*H..Ct)

D S R - 12

-NHCO

c, ^r .-p-c,,,

NHC0CH 2 0-*
CO

CO0H Cfi
D S R - 13

c»Hi,ct)

NHC0CH 3

C i i Hi

N N H

D S It - 14

C1I

■yVH

N H ^CCH

D S R - 15

CH

W N N CH, NHSO:

0C e H l

W N — :N CH,

D S R - 16

0C,H,,Ct)

(OCJh

C 3 fU
I

OCiiCONH

0

OH
OH

D S R - 17

OH

^J^CONHCCH,) t 0'^J^-C 5 H l ,Ct)

WJx^ c,h m CO

NHSO 4 -\ VOCeHm

D S R - 18

D S R - i9

-486-

on

NHCHCCH ) ) 1

0

CH* V CH,

S R - 20

D S R -23

»BB¥2-35450

NHS0tC 4 Hi

D S R "30

OH

S R -

?f B3¥2-3545Q (12)

D S R -32

OH

OC M H S5

NHSO^CCH^x

D S R » 33

Ct)C,H,r

OH ^™

"ff ^T^^

C
t

-OCHCONl

0

D S R - 34

tfHCKCCHOs

*) gp £ U < 1 x 10"' - 1 x 10''^ A- I ^ 5 o

c n ^> <?> DSRft & ^ £ * ft m K & 4 ^ * ^ * ft

& k it v & ostHt ^«t?3&t7^Ayisr®tt-c«>4»
v& & & it , T}\sftv&mmtLxmitnLxi > £<,

^1g&T?i>&*#*=l±, W If # a » 2,322,02
7** R2, SOI, 170*, R2,8Gl,i7I^> R 2,272,I

DSR ft & ft fr * » & » » '= * & IS K t£ C T f& $

¥ v ft AS ?L ffl K i6 2n t 6 do d< * L v v .

_t JB tf> DSRte 4iHi * # 58 SB 57- 1 38633^ * R 57
-155537^, 1^57-171334^, P53~1194I^v R61
-53643*, PI 6 1 -34 646 ^ , FI 61-86751^ . 13 6 1-1
02 646 ^f- , ^6 1 - 1 026 47^. R61- 10724S^, R 6 I -
1 1 30 60 * ffi tt S ft # ffi J: t 1* f& i~ £ -

D S R - 35

OH

oqr™

o

NHSG t N(C,H») 3

D S R - 36

OH /? — !\
%>A^ CsH,,Ct)

DSRft & ttM4 * Slf $ <0 7 x / ~ A- & C T v A ^
? ^ t (a; - ft! k ffl ^ X t M m *t> K M r 6 £ ^

* ff3feu<iiR-» p l a ^±^»

^ K t! S 6 . 3: fcRGDSRrffc

* & W « !S5 3fe ft *= $ ^ * " N Q y ^ & ¥L $ *
U r ii v $ AT ^ a <r v ft & *L ?PJ ^ & « *> *> £
J5 ^ 4 C £ ^ t 3 4 .

SL 5M I* # £ K J: $ it ¥ m & ? & ^ t & X $ ,

■c £ 6 „

® $ «p K 0 * L *

^ cr y ^ ft ^ ffl ii , / 'J 15 It I , K ^ 5SU

*UDi*^^^^' ^ II ^ ^< ^ v ^ - <t

U r 14 , -tr ? ^ *^ =§r ^ ^ v s ^ * s ^ x *> ^ °

*L W , ^Offitf)i7^{4^ o ^ K H « , Wm?

& Z t & X $ , X * *1 M ffl > ?K^^^Xi±^^&

^ flt .1? y ^ - ^ 5Mft ftr C ? r * £ * ) ^r^^^^

■488-

» Rfl¥2-35450(13)

jpj v AoyntSSffl, » fe 3W ^ « R » » A / U C * SK $ )

», »n>t«, K ttT MHcn*JII!t*#»s«llt«.

£/ % as ffi <o j: -? a ^ k « k # jb 4- 7 7 ✓ ^ v h 4 < as « « i >

4> j;: [± K & & si 4 1 k ® * *t J** 1 « tH -f 4 * t

t 4 it ^ o y ■/ ft a r (/ 3 m p r ir t i; 1 t

**»*♦(=.*!*, * A. - » V * * * V * * - , ******* VK^* *

* * « 6 m . v h *1 , » * . ii®*^ * « * * > X * * ft * K -> ^ X tt H - » * » ~ « * *
ig 14 ffl v ft * t"J » it JW , « « » M . * « » * ,fc|lt^ft?««** tSbfc '

j jg ( u - v b v ib J9 )

- 0.2

£ f# & i: t T ii , t: 'J x f i> ^ f t 7 ~ I- M ^ a 4 ^

tz , # l ) ^ ^ ^ ^ ^ ^ 7 9 ^ ~ ^ 7 4 & S± ■> ? * ^

a -0-06

— 0.2

*fc^^SSft##fcffl^^fe*K#*f!l*Kli UV-2

„ , , | —0.02

0 ||- 2

2 S ( 4 s m ® ) ft & ft & ?l ^ t As 1 7 * ^ % , ft^ & A E i I! i$

ft*?Afb0 (^^ 0.07/. O -0,15 fliai0.6M^«*l»««»**25«

i ,0 £ ^ & S -0*7

-0.6

■tf ^ ^ v

c a - 0.02 # * r >

0 ll« t -0.1 S D - I -1-0* 10-*

^31 Cm I !& ?L #1 )

s D 2 - S.OxiO" 4

\ - *

fc£ft#*LffiCAer6*^9*,fi«ftA*rSJ*fe S D - 3 -1.0*10"

IS ^ & 0-3* ffi £ & O 35 » & &29^ C p- 2 -0.04

$& V (ft a -0.4 Cp- 3 -0.24

- 0,6 Cp- 4 b'Zi

.» L . 0 x 10 " * C p™ 7 -0.04

-3.0x10'* O i I — 1 -0.15

... 1 .0 x 10" s 0 i I- 3 -0-02

Cp _ 2 -0.03 ® 5 ^ C ^ 3 i ^ ¥1 M H )

c p _ 3 -0.06 m & it ffi ¥1 flf ( Ael 8 * ;u % , f*| Sft A A s E S£ #

-.-0.06 ffl ^ fi£ 0.3 /* ru * *S £ S ^> St » « & 16%

-0.03 "'1-0

-0.03 -if 7 f '/ -1*0

-0.012 S D - I — 1.0xl0~*

3 D ~~ 2 3.0x10"*

■if J f- V

S D ^ 1

5 D - 2

S D ™ 3

C p— 4
C 7

0 i t — 1
O i J — 3

-489-

RBI ¥2-35450 (14)

S D ~ 3

...

! . 0 x 10" fr

O i 1- 1

-0.5

Cp-5

•» 0,

05

$ 4 ffl C $f 2 & & *L #J $ )

Cp~6

- 0 .

1

i* jMt a ft a* 1

C A g 1 7 ^ ^ 5

0 I 1— I

■» Q .

01

$ g 0

,6 $1 is, J* & S

e ffi SBt 25*5

Oil — 2

- 0,

05

& =fr SS S

-0,4 .

G 15 ( 4 1 HQ fl

3 )

^ 7 f >

-0-5

■tf "* V

- I .

0

S D - 4

- 5 .

Ox 10**

A S — 1

- 0 .

03

S D — 5

- 2 .

Ox t0~ *

0 i 1 — I

- 0 -

05

S D - 6

■•■ 0 ,

3 x 10- 4

7 JSf C ^ I 1

a & ft 3W « )

Cp-8

- 0,03

5c H -It: « ft i)

PJ C A g I 6 * ^ % <

t ft U A Ag I I

g i*

Cp-9

- 0,25

m ^ \

: (?> « ft ft fit 28%

C p-10

- 0,015

&t & 3fc

»- a .

C p— 14

-0,01

1 .

J

O i i — 1

-0.2

S D ~ 4

■ 5,0 x 10'*

m 9 ffl C # 3 « ?!

s ft m m )

S D — 5

- 2. Ox I0-*

m & <t a ft m

% , ft

ft a« j m as

g 0 — 0

• G.3* 10"*

& $t €1 I

. 0 r a* $ ^ ^ ^ <7> i

C p— 8

- 0

.03

»■ G-S5

C p— 9

- 0

.2

-tf 5 f v

- I . 0

C p- 14

»• 0

.02

S 0 - 7

5 x 10" 4

S D — 8

-

* 1 ,4 * 10' +

C p— 16

-0.9

Cp-8

- 0

.02

O i 1 - I

C p™ 1 1

■» 0

.01

as ft isi m >

C p- 12

»■ 0

.0 J

R Sk <£ « ft 38

C Ag! 1 0 *

% s

C p-13

... o

.20

a ^ ^

I . 3 i" n, flc ^ ^

% ffi f% St 22^

C p~ 15

•» 0

.015

% ^ a ft

-0.5

O M - I

.» 0

.20

-0.6

O i i — I

- D

,05

S D — 9

- 1

.Ox

f ton ( *f *

)

C p-IB

- 0 .25

^ 7 f >

- i

,2

O i 1 — I

-0.07

K &

-» o

,08

m nm c m i «

A S — 2

- 0

« 1

■e ^ f- *

- 0.3

0 i 1 - t

... o

.3

U V — 1

-0,1

% lift C $ t

If « ft 8* «)

U V - 2

-0.2

0c H ft * ft

#J ( A g I 7 *r ^ %

, F*i {ft ft Act

O i \ - L

- 0.02

^ G , 5 n * St *SH

& <D & 6S & & 15%

O i 1 - 2

- 0,02

% # St

»■ 0

, 4

it 14E ( & 2 ®

XI J* )

- 1

,0

ft & ^ & it m

{ T St fg 0.

. 07 m i3

)

S D — 9

■» 2 . 0 x I 0 ~ *

#1 % =Hr £fc

- 0,5

C p- i 4

»• 0

t . 07

if V * >

- 0-4 5

-490-

»ISt¥2-35450 (15)

CI@1.5^ ■) -0.2

H - 1 -0-4

C pd~ A -0,5

C p4- B —6.5

fotz * & # 1 Q 1 <?> 38 3 , 4, 5 I « ^ 7 ^
DSRffc&^££nJC^&#i02~109£f1 T l5Stl'fco

& 1

is: *4

No,

$5 ®

ffi

101

Cp— 3
Cp-4

Cp-3
Cp-4

Cp-5
Cp-6

it ■**

102

Cp— 3
Cp~20

Cp- 3
Cp-20

Cp-21
Cp—6

tf

103

Cp~4
ffijjji 5

Cp-4
Mm 5

Cp-5
I

tt

104

Cp~3
Cp— 4

Cp™3
Cp— 4
DSR-24(G.2G)

Cp™5
Cp— 6
DSR-24C0.05)

tf

105

Cp— 4

Cp-4

mm 5

DSR~24(0*20)

Cp™5
wm 12

D5S-24CG.05)

106

mm 5
DSR~18(G-06)

Cp™4

mm 5

<p\m 4

107

Cp™ 3
DSR-35C0.06)

0*m 7

DSR-32CG-20)

mm s

PSK-32(0,04)

//

ioa

Cp- 3
Cp-19
DSR-19(0.06)

Cp-20
DSR- 19(0-22)

9im 14

DSR- 19(0. 05)

tt

109

mm 5

j DSR-25C0.06)

fam 3

DSR-17C0.2I)

mm 12

DSR~22(G.05)

at ic * & m c m ^ ^ & $ <o it # & it * x u ft

^ £ £ T S3 K # t •

Cp— 3

u v - i

U V — 2

CHj CH,

CM

x/y- 7/3CflEft It)

Cat!* '

■ CO0C»H,

COC,H.

Cp— 4

COC s H lt

iCHCONH

CI ICON U y
C,H Ja

OH

C ( H,,Ct) ^K/'

NHCONH

CN

OK

C,H„<0 ^j/™

CH

on- i h y ? w^a-
oil- 2 -? ? ^mv^r^

Cp— 2

CsHi.CO

Cp-5

HjC—C-CHj
CH?

C(CHOj

-491-

33 IS! ¥2-35450 (16)

Cp™6

Cp-7

Ct)C*Hi t -

OH

C0NHC !6 Ei,j

OCHjCHiSCHCzCOOH

OH

x- 1

-coo

€HCONB\

I

COOC+H,

CONH jp

V

Cfl

Cp™ 10

ca

a- 25

CH,

C, ,H 2I C0NH

N-N-

CG

Cp-U

OC*H,

CCHi> s CO)NH— j r~S-

C a H, t Ct)

Cp-12

(t)C,H|

Cp™!3

Ct)C»H M

Cp- 14

Cfl,

Ci jH IS OCOCNOOCv

Ct)C,Hi,

C*H fi
GCHCONft

C,H M <t)

o-

CONtf-

N ^0

X yOa

Cfl

CONii"

Cfl\ X

Cfl

CH 3

■COOCHCOOCxHx

-NHCOCHCONH-

CO—-0

Cp— 15

NH00(CH,>»0-^^»C 4 H, i<0
(CH , ) jCCOCHCONH-"^^ C t H , , C t )

CG

if
i

Cp~l6

CH

W I

Cfl

JL

C0OC I3 H 35

Cp-!7

HO

CjHs0 1 K CH*

09

NHCONHyk C.HmCO

T^NHCOCHO™/ V-CfHnCt)

C.H*

492™

»ffl ¥2-35450 (17)

Cp-18

cn

Cp-19

C*HtO,S-

Cp— 20

OH

NHCONHv^L

Cp™21

CiHuCt)

t

CHiCOOCfi*

OH

C.HnCt)

L 1 V™^

OR

c 4 iif0C0Nn

CsHt

OONHC-CH*> a OC It Ht*

OH

CGtJHC f H,

C<H,OCONH OCHjCHjSCHC^His
COOH

A S — 1

S D — 1

5 D — 2

OH

Ci sHj

"GjNa

OH

OH

(sec)C*H i t-

s Ht r(sec)

OH

(CBi) 3 SO> 9

CCHj),SO t H-

S D— 3

S D— 7

S D— 4

S D — 5

S D— 6

(CHO»SO s H*N(iHOj

(CH,0,SOr

--Co.

(CH,)jS0 3 Na

C ? H B

:H-CH-CH

CCHa)*SOi*

CCH 3 )«S0»°

C!

■CKj

Hi

S D — 8

CF

S D — 9

Cfi*

H - I

C 2 H S

(CJIj)aSOiNa

C S H S
I

N

(CHO

H-CH-CK

CCHi) 4 SO>Ma

CCH s )*SOj e

(CHO^SOjNa

CH a -CH~SQi— CH 4 ™C0NH"-™CH a
CHj^CH— SO CH,— CONH™CH :

-493™

» IB ^2*35450 (18)

C pd — A

Cpd-B

i , i - ^

V

3 . 3g

H

i

ff

% & jr

y

■7

A

4 . Og

&t #

u

■7

A

30 . Og

H

A ft a

y

A

i . 4e

ft ft #

y

•7

A

\ - 3 ra B

v f 1 i 1 ^ , aft

t: K n

7

5 v Gl ft

a

2.4e

7 4 ;u

% , 7 v -r V 7 ^ ^

4*( N *

}V

- M

- £ - fc K

# - No . 26)

x iv

r

/

) -

2 - > *■ ^

r

"J

® ft

& ffe » £ ffl

r , T IE tf>

4 - 5g

m ® & & * ff

if- £ SB

T

ft 3

r> i

5 &

PR

10.0

m 6

# 3

0 #

< $E £ $f

>

* 4

fr 2

0 ®

x f- u

T

pa ^ m

Iff

r

>- ^ - ^ A

& 3

5?- i

5 *fr

1 20 . Og

55 1

# 0

5 #

^ =h v>

T

y m mm

h

y

■7 A g

m

tW; JSL & Iff

10 -0s

& it Y

■7

A

150 . 0g

>-

•7

A

10 . Ge

2 . 0g

?K £ #r £ r

1.0ft

< 5E 31 AS )
^^^^h'J*7A

£ 3E 51 ^ ^ h y A

< £ 5£ $ >

y ^ 'j ^ (40% )
# y * * ^ * *• u >

^ 4- SO A T

6.0

n 7- ^ y $ a ^
1-0 e
4.0 g

£ $ <70% )

200 * Owfl
4-6 g
1.0ft
6.6

2 . Oitttf

7 — JU-7 x^WU

^ 10) 0.3g
I .Ofl

C n fl) lit n , X-r i left m 310S! ft IE gf 4r ^

^ x m & m s u . ^^^^ €^ ^j^^ ^^^^^ ^ ^^5^ ^ j_ ^^^^ p^^p

*otta»K«r*ji>5ft2(i^Uft: B fe » & # 'J% *

^ @ , & n m ^ j*« a ^ »

^ 2 m h ft ^ * i= > ^ % m <n m & <n ft w «
liK ^ a ^ c ^ a ^ n t ^ ^ B
m 2

RMS x 1000

fit n

101

0,69

30

it m

102

0.67

31

ff

103

0,66

30

tr

104

0.67

28

ff

105

0.60

25

106

0.59

26

/f

107

0.56

26

ff

103

0.62

25

ff

1G9

0,57

26

^yK38£ffi^ & % m <n % & & U ft

h n tz .

494